By Andreea Irina Barzic, Silvia Ioan
Phase morphology in multicomponent polymer-based platforms represents the most actual attribute that permits for regulate of the fabric layout and implicitly the advance of recent plastics. Emphasizing homes of those promising new fabrics in either answer and strong part, this ebook describes the coaching, processing, houses, and functional implications of complicated multiphase platforms from macro to nanoscales. It covers a variety of platforms together with copolymers, polymer blends, polymer composites, gels, interpenetrating polymers, and layered polymer/metal buildings, describing features of polymer technological know-how, engineering, and expertise. The e-book analyzes experimental and theoretical features in regards to the thermal and electric shipping phenomena and magnetic homes of an important significance in complex applied sciences. It stories the newest advances relating morphological, rheological, interfacial, actual, fire-resistant, thermophysical, and biomedical homes of multiphase polymer structures. Concomitantly the booklet offers with simple research ideas which are delicate in elucidating the beneficial properties of every section. It additionally discusses the most recent examine developments that provide new ideas for complex bio- and nanotechnologies.
- Introduces an outline of contemporary reviews within the region of multiphase polymer platforms, their micro- and nanostructural evolutions in complex applied sciences, and offers destiny outlooks, new demanding situations and opportunities.
- Discusses multicomponent constructions that supply more suitable actual, mechanical, thermal, electric, magnetic, and optical houses tailored to present necessities of recent applied sciences.
- Covers quite a lot of fabrics, similar to composites, blends, alloys, gels and interpenetrating polymer networks.
- Presents new ideas for controlling the micro- and nanomorphology and the mechanical houses of multiphase polymeric materials.
- Describes assorted purposes of multiphase polymeric fabrics in a number of fields, together with car, aeronautics and house undefined, screens, and medicine.
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Extra resources for Multiphase polymer systems: micro- to nanostructural evolution in advanced technologies
1996, 1997) reduced the full Palierne model to linear dynamic moduli in which the two relaxation processes are present, offering values for the shape relaxation time, ts, as well as for the interfacial relaxation time, tβ. The influence of compatibilizer concentration on the two relaxation times also was analyzed by Van Hemelrijck et al. (2004). They have fitted the Palierne model with an interfacial shear modulus by introducing a concentration gradient of the block copolymer along the interface.
2000). It was also noted that the viscoelastic properties are susceptible to phase behavior, in which case, the time–temperature superposition fails, marking the beginning of phase separation. The activation energy for these two regions is lower than for single-phase systems, although the additional relaxation mechanism (not present in the homogeneous region) can be a marker of phase separation. The nonlinear viscoelastic properties’ dependence on the shear rate and hysteresis observed in the thixotropic loops also confirms the presence of inclusions in the region of phase separation.
2014). Zeta potential of the micelles is measured using a phase analysis light scattering zeta potential analyzer. Before the measurements, the micelle formulations are dialyzed against buffer solution to remove NaCl ions. 2) Macromolecular Architectures of Copolymer Solution Assemblies 29 where z is the zeta potential, m is the mobility, e is the dielectric constant, and h is the absolute viscosity of electrolyte solution (Sezgin et al. 2006). , nuclear magnetic resonance) (Forster and Plantenberg 2002).
Multiphase polymer systems: micro- to nanostructural evolution in advanced technologies by Andreea Irina Barzic, Silvia Ioan